Why Is Terephthaloyl Chloride 100-20-9 Critical in Modern Chemical Applications?

2026-03-30 - Leave me a message

Terephthaloyl Chloride (CAS 100-20-9) is a key intermediate in the production of high-performance polymers, particularly in the manufacture of polyethylene terephthalate (PET) and liquid crystalline polymers (LCPs). Its purity, stability, and reactivity are crucial for industrial applications. This article provides a detailed overview of Terephthaloyl Chloride, including its properties, applications, handling, and sourcing solutions provided by Xiamen Aeco Chemical Industrial Co., Ltd.

Terephthaloyl Chloride (CAS 100-20-9)


Table of Contents


Introduction to Terephthaloyl Chloride

Terephthaloyl Chloride (100-20-9) is an aromatic diacid chloride derived from terephthalic acid. Due to its high reactivity, it serves as an essential building block in polymer chemistry. Xiamen Aeco Chemical Industrial Co., Ltd. specializes in supplying high-purity Terephthaloyl Chloride for various industrial needs.

  • CAS Number: 100-20-9
  • Molecular Formula: C8H4Cl2O2
  • Molecular Weight: 163.03 g/mol
  • Appearance: White crystalline solid

Physical and Chemical Properties

Understanding the properties of Terephthaloyl Chloride is essential for handling, storage, and industrial usage.

Property Description
Melting Point ≈ 105–108 °C
Boiling Point ≈ 305 °C (decomposes)
Density 1.4 g/cm³
Solubility Insoluble in water; soluble in organic solvents like dichloromethane, chloroform
Reactivity Highly reactive with moisture, alcohols, and amines

Manufacturing and Production Methods

Industrial production of Terephthaloyl Chloride is mainly carried out through the chlorination of terephthalic acid using thionyl chloride or phosphorus pentachloride. Xiamen Aeco Chemical Industrial Co., Ltd. ensures the process delivers high purity (>99%) suitable for polymer-grade applications.

  • Thionyl Chloride Method: Efficient and widely used for large-scale production.
  • Phosphorus Pentachloride Method: Less common, suitable for specialty applications.
  • Purification: Recrystallization and vacuum distillation ensure minimal impurities.

Key Applications in Industry

Terephthaloyl Chloride plays a pivotal role in the following sectors:

  • Polyester Manufacturing: Essential in producing PET fibers and resins.
  • Polyamide and LCPs: Used to make high-strength and heat-resistant polymers.
  • Coatings and Adhesives: Serves as a precursor in specialty coatings and functional adhesives.
  • Pharmaceuticals: Intermediate in drug synthesis where aromatic acylation is required.
Application Industry Key Benefits
Polyester Fibers Textile & Packaging High strength, durability, transparency
Liquid Crystalline Polymers Electronics & Automotive Heat resistance, dimensional stability
Specialty Coatings Industrial Surface Coatings Enhanced adhesion, chemical resistance

Handling and Safety Considerations

Due to its high reactivity with water and moisture, Terephthaloyl Chloride requires strict safety protocols:

  • Store in a dry, cool, well-ventilated area, away from moisture.
  • Use protective gloves, goggles, and chemical-resistant clothing during handling.
  • Ensure proper waste disposal according to local regulations.
  • Immediate neutralization of spills with appropriate dry absorbents is recommended.

Xiamen Aeco Chemical Industrial Co., Ltd. provides detailed MSDS and handling guidance to ensure safe industrial use.


Quality Standards and Supplier Selection

High-purity Terephthaloyl Chloride is critical to avoid polymer defects or side reactions. Key quality indicators include:

  • Purity ≥ 99%
  • Low moisture content (<0.05%)
  • Consistent particle size for even reactivity
  • Reliable packaging to prevent hydrolysis

Choosing suppliers like Xiamen Aeco Chemical Industrial Co., Ltd. ensures reliable quality, timely delivery, and technical support for process optimization.


Terephthaloyl Chloride vs Other Acid Chlorides

Compared to other aromatic acid chlorides, Terephthaloyl Chloride offers unique advantages:

Property Terephthaloyl Chloride Benzoyl Chloride Isophthaloyl Chloride
Polymer Compatibility High (PET, LCP) Moderate High (specialty polymers)
Reactivity High High Moderate
Thermal Stability Excellent Good Good

Frequently Asked Questions

Q1: What is the main use of Terephthaloyl Chloride 100-20-9?
A1: Its primary use is in producing PET resins, fibers, and high-performance polymers like liquid crystalline polymers.
Q2: How should Terephthaloyl Chloride be stored?
A2: Store in a sealed container in a cool, dry place, away from moisture and reactive chemicals.
Q3: Is it dangerous to handle Terephthaloyl Chloride?
A3: Yes, it reacts with water and alcohols. Proper PPE and handling protocols are essential.
Q4: How can I ensure the quality of Terephthaloyl Chloride?
A4: Choose reputable suppliers like Xiamen Aeco Chemical Industrial Co., Ltd., and check for purity, moisture content, and certification.
Q5: Can it be used in pharmaceutical applications?
A5: Yes, it is sometimes used as an intermediate in specific chemical syntheses under controlled conditions.

Conclusion and Sourcing Information

Terephthaloyl Chloride 100-20-9 is indispensable in modern polymer chemistry due to its reactivity, stability, and versatility. Partnering with experienced suppliers like Xiamen Aeco Chemical Industrial Co., Ltd. ensures high-quality materials, technical support, and timely delivery. Whether your application is in polyester production, liquid crystalline polymers, or specialty chemical synthesis, sourcing from reliable providers mitigates risks and enhances production efficiency.

For high-purity Terephthaloyl Chloride, expert guidance, and competitive pricing, contact us today and discover tailored solutions for your industrial needs!

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